Poly[bis(1-carbamoylguanidinium) [tri-μ-chlorido-dichloridobismuthate(III)]]
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منابع مشابه
Poly[bis(1-carbamoylguanidinium) [tri-μ-chlorido-dichloridobismuthate(III)]]
The structure of the title organic-inorganic hybrid compound, {(C(2)H(7)N(4)O)(2)[BiCl(5)]}(n), consists of corrugated chains parallel to [100] of corner-joined [BiCl(6)] octa-hedra, separated by layers of organic 1-carbamoylguanidinum cations. The crystal cohesion is achieved by N-H⋯O and N-H⋯Cl hydrogen bonds, which link the organic and inorganic parts of the structure.
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The mol-ecular geometry of the complex cation in the title structure, [(μ-Cl)(3){Ru(II)(η(6)-C(6)Me(6))}(2)][Fe(III)Cl(4)], compares very well with that reported earlier for the corresponding PF(6) (-) salt [Pandey et al. (1999 ▶). J. Organomet. Chem.592, 278-282]. The [FeCl(4)](-) counter ion has a rather regular tetra-hedral geometry with Fe-Cl distances and Cl-Fe-Cl angles in the range 2.189...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2012
ISSN: 1600-5368
DOI: 10.1107/s1600536812015668